Publications

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2026

• Oxygen effects on passive film evolution and metastable pitting in 316L stainless steel using SECCM
  L. Coelho, D. Torres, M. Bernal, L. Malet, A. Makogon, F. Kanoufi, V. Shkirskiy, J. Ustarroz
  Corrosion Science, 113708, (2026)
  https://doi.org/10.1016/j.corsci.2026.113708, bib file

• A Novel Method for Hydrogen Permeation Detection Using Reflective Microscopy and Machine Learning
  A. Makogon, F. Kanoufi, V. Helbert, F. Vucko, V. Shkirskiy
  Analytical Chemistry, (2026)
  https://doi.org/10.1021/acs.analchem.5c06160, bib file

2025

• Machine learning-enhanced optical monitoring for identifying pitting-susceptible zones in 316L stainless steel
  A. Makogon, L. Coelho, J. Ustarroz, P. Decorse, F. Kanoufi, V. Shkirskiy
  Corrosion Science, 256, 113184, (2025)
  https://doi.org/10.1016/j.corsci.2025.113184, bib file, citations: 5

• In Situ High-Resolution Optical Microscopy Survey of the Initial Reactivity of Multiphase ZnAlMgSi Coating on Steel
  G. Sartori, O. Gabsi, T. Amorim, V. Shkirskiy, P. Volovitch
  Metals, 15(8), 821, (2025)
  https://doi.org/10.3390/met15080821, bib file

2024

• Key requirements for advancing machine learning approaches in single entity electrochemistry
  V. Shkirskiy, F. Kanoufi
  Current Opinion in Electrochemistry, 46, 101526, (2024)
  https://doi.org/10.1016/j.coelec.2024.101526, bib file, citations: 7

• Initial cathodic reactivity of intermetallic particles in 7175 aluminum alloy buried under 6 µm thick anodized oxide layer revealed by in-situ reflective microscopy
  F. Raffin, A. Makogon, F. Kanoufi, J. Echouard, V. Shkirskiy, P. Volovitch
  Electrochimica Acta, 492, 144155, (2024)
  https://doi.org/10.1016/j.electacta.2024.144155, bib file, citations: 5

• Is Unsupervised Dimensionality Reduction Sufficient to Decode the Complexities of Electrochemical Impedance Spectra?
  A. Makogon, F. Kanoufi, V. Shkirskiy
  ChemElectroChem, 11(7), (2024)
  https://doi.org/10.1002/celc.202300738, bib file, citations: 10

• Deciphering the Interplay between Local and Global Dynamics of Anodic Metal Oxidation
  A. Makogon, J. Noël, F. Kanoufi, V. Shkirskiy
  Analytical Chemistry, 96(3), 1129-1137, (2024)
  https://doi.org/10.1021/acs.analchem.3c04160, bib file, citations: 7

2023

• Use of Boron Doped Diamond Corrosion Free Supports to Evaluate Fuel Cell Electrocatalyst Stability Under Accelerated Stress Testing
  D. Houghton, P. Zhao, Y. Han, R. Beanland, J. Macpherson, L. Godeffroy, V. Shkirskiy, F. Kanoufi, J. Sharman
  ECS Meeting Abstracts, MA2023-01(38), 2232-2232, (2023)
  https://doi.org/10.1149/ma2023-01382232mtgabs, bib file

• Unsupervised Analysis of Optical Imaging Data for the Discovery of Reactivity Patterns in Metal Alloy
  R. Li, A. Makogon, T. Galochkina, J. Lemineur, F. Kanoufi, V. Shkirskiy
  Small Methods, 7(10), (2023)
  https://doi.org/10.1002/smtd.202300214, bib file, citations: 18

• Imaging and Quantifying the Chemical Communication between Single Particles in Metal Alloys
  L. Godeffroy, A. Makogon, S. Gam‐Derouich, F. Kanoufi, V. Shkirskiy
  Analytical Chemistry, 95(26), 9999-10007, (2023)
  https://doi.org/10.1021/acs.analchem.3c01258, bib file, citations: 26

• Reflective microscopy for mechanistic insights in corrosion research
  V. Shkirskiy, F. Kanoufi
  Current Opinion in Electrochemistry, 39, 101259, (2023)
  https://doi.org/10.1016/j.coelec.2023.101259, bib file, citations: 14

• Aryldiazonium reduction mechanism deciphered by scanning electrochemical microscopy through an EC’ process
  N. Kostopoulos, V. Shkirskiy, C. Combellas, F. Kanoufi, T. Breton, J. Noël
  Electrochimica Acta, 444, 142028, (2023)
  https://doi.org/10.1016/j.electacta.2023.142028, bib file, citations: 1

• An innovative method for controlled synthesis of bicomponent monolayer films obtained by reduction of diazonium
  J. Billon, A. Omelchuk, V. Shkirskiy, S. Dabos‐Seignon, O. Alévêque, E. Levillain, T. Breton, C. Gautier
  Nanoscale, 15(47), 19213-19218, (2023)
  https://doi.org/10.1039/d3nr03946c, bib file, citations: 3

• Fuelling electrocatalysis at a single nanoparticle by ion flow in a nanoconfined electrolyte layer
  L. Godeffroy, V. Shkirskiy, J. Noël, J. Lemineur, F. Kanoufi
  Faraday Discussions, 246, 441-465, (2023)
  https://doi.org/10.1039/d3fd00032j, bib file, citations: 4

• Aryldiazonium Reduction Mechanism Deciphered by Scanning Electrochemical Microscopy Through an Ec’ Process
  J. Noël, N. Kostopoulos, V. Shkirskiy, C. Combellas, F. Kanoufi, T. Breton
  SSRN Electronic Journal, (2023)
  https://doi.org/10.2139/ssrn.4329602, bib file

2022

• Screening the Surface Structure-Dependent Action of a Benzotriazole Derivative on Copper Electrochemistry in a Triple-Phase Nanoscale Environment
  E. Daviddi, V. Shkirskiy, P. Kirkman, M. Robin, C. Bentley, P. Unwin
  The Journal of Physical Chemistry C, 126(35), 14897-14907, (2022)
  https://doi.org/10.1021/acs.jpcc.2c04494, bib file, citations: 27

• Bridging the Gap between Single Nanoparticle Imaging and Global Electrochemical Response by Correlative Microscopy Assisted By Machine Vision
  L. Godeffroy, J. Lemineur, V. Shkirskiy, M. Vieira, J. Noël, F. Kanoufi
  Small Methods, 6(9), (2022)
  https://doi.org/10.1002/smtd.202200659, bib file, citations: 38

• No more compromise: a facile route towards functionalized surfaces with stable monolayers
  J. Billon, V. Shkirskiy, S. Dabos‐Seignon, T. Breton, C. Gautier
  Physical Chemistry Chemical Physics, 24(23), 14294-14298, (2022)
  https://doi.org/10.1039/d2cp02129c, bib file, citations: 7

2021

• From Monolayer to Multilayer: Perylenediimide Diazonium Derivative Acting Either as a Growth Inhibitor or a Growth Enhancer
  V. Shkirskiy, J. Billon, E. Levillain, C. Gautier
  Langmuir, 37(44), 12834-12841, (2021)
  https://doi.org/10.1021/acs.langmuir.1c01808, bib file, citations: 8

• Detection and quantification of defect evolution at buried metal-oxide-polymer interface on rough substrate by local electrochemical impedance mapping
  T. Sanchez, E. Kurchavova, V. Shkirskiy, J. Światowska, V. Vivier, P. Volovitch
  Electrochimica Acta, 388, 138467, (2021)
  https://doi.org/10.1016/j.electacta.2021.138467, bib file, citations: 9

• Capacitive Impedance for Following In‐Situ Grafting Kinetics of Diazonium Salts
  V. Shkirskiy, E. Levillain, C. Gautier
  ChemPhysChem, 22(11), 1074-1078, (2021)
  https://doi.org/10.1002/cphc.202100154, bib file, citations: 5

2020

• Nanoscale electrochemistry in a copper/aqueous/oil three-phase system: surface structure–activity-corrosion potential relationships
  E. Daviddi, V. Shkirskiy, P. Kirkman, M. Robin, C. Bentley, P. Unwin
  Chemical Science, 12(8), 3055-3069, (2020)
  https://doi.org/10.1039/d0sc06516a, bib file, citations: 64

• New experimental approach for intelligent screening of buried metal/oxide/polymer interfaces via local electrochemistry: Example of undamaged model epoxy-coated Zn alloys
  T. Sanchez, S. Gillet, V. Shkirskiy, V. Vivier, J. Echouard, J. Światowska, P. Volovitch
  Electrochimica Acta, 367, 137411, (2020)
  https://doi.org/10.1016/j.electacta.2020.137411, bib file, citations: 4

• High pressure high temperature synthesis of highly boron doped diamond microparticles and porous electrodes for electrochemical applications
  G. Wood, C. Zvoriste-Walters, M. Munday, M. Newton, V. Shkirskiy, P. Unwin, J. Macpherson
  Carbon, 171, 845-856, (2020)
  https://doi.org/10.1016/j.carbon.2020.09.038, bib file, citations: 45

• Electrochemical Impedance Measurements in Scanning Ion Conductance Microscopy
  V. Shkirskiy, M. Kang, I. McPherson, C. Bentley, O. Wahab, E. Daviddi, A. Colburn, P. Unwin
  Analytical Chemistry, 92(18), 12509-12517, (2020)
  https://doi.org/10.1021/acs.analchem.0c02358, bib file, citations: 32

• Corrosion Inhibition at Scribed Locations in Coated AA2024-T3 by Cerium- and DMTD-Loaded Natural Silica Microparticles under Continuous Immersion and Wet/Dry Cyclic Exposure
  P. Denissen, V. Shkirskiy, P. Volovitch, S. García
  ACS Applied Materials & Interfaces, 12(20), 23417-23431, (2020)
  https://doi.org/10.1021/acsami.0c03368, bib file, citations: 22

• Nanoscale Scanning Electrochemical Cell Microscopy and Correlative Surface Structural Analysis to Map Anodic and Cathodic Reactions on Polycrystalline Zn in Acid Media
  V. Shkirskiy, L. Yule, E. Daviddi, C. Bentley, J. Aarons, G. West, P. Unwin
  Journal of The Electrochemical Society, 167(4), 041507, (2020)
  https://doi.org/10.1149/1945-7111/ab739d, bib file, citations: 74

2019

• Development of anodic and cathodic blisters at a model Zn/epoxy interface studied using local electrochemical impedance
  V. Shkirskiy, A. Krasnova, T. Sanchez, A. Amar, V. Vivier, P. Volovitch
  Electrochemistry Communications, 111, 106633, (2019)
  https://doi.org/10.1016/j.elecom.2019.106633, bib file, citations: 5

• Nanoscale electrochemical visualization of grain-dependent anodic iron dissolution from low carbon steel
  L. Yule, V. Shkirskiy, J. Aarons, G. West, B. Shollock, C. Bentley, P. Unwin
  Electrochimica Acta, 332, 135267, (2019)
  https://doi.org/10.1016/j.electacta.2019.135267, bib file, citations: 74

• Nanoscale Active Sites for the Hydrogen Evolution Reaction on Low Carbon Steel
  L. Yule, V. Shkirskiy, J. Aarons, G. West, C. Bentley, B. Shollock, P. Unwin
  The Journal of Physical Chemistry C, 123(39), 24146-24155, (2019)
  https://doi.org/10.1021/acs.jpcc.9b07216, bib file, citations: 83

• Effect of pH on Mg(OH)2 film evolution on corroding Mg by in situ kinetic Raman mapping (KRM)
  A. Maltseva, V. Shkirskiy, G. Lefèvre, P. Volovitch
  Corrosion Science, 153, 272-282, (2019)
  https://doi.org/10.1016/j.corsci.2019.03.024, bib file, citations: 110

• On the Time Resolution of Electrochemical Scanning Flow Cell Coupled to Downstream Analysis
  V. Shkirskiy, F. Speck, N. Kulyk, S. Cherevko
  Journal of The Electrochemical Society, 166(16), H866-H870, (2019)
  https://doi.org/10.1149/2.1401915jes, bib file, citations: 20

2018

• Cathodic driven coating delamination suppressed by inhibition of cation migration along Zn|polymer interface in atmospheric CO2
  V. Shkirskiy, M. Uebel, A. Maltseva, G. Lefèvre, P. Volovitch, M. Rohwerder
  npj Materials Degradation, 3(1), (2018)
  https://doi.org/10.1038/s41529-018-0064-z, bib file, citations: 13

• Nanoscale Electrochemical Mapping
  C. Bentley, J. Edmondson, G. Meloni, D. Perry, V. Shkirskiy, P. Unwin
  Analytical Chemistry, 91(1), 84-108, (2018)
  https://doi.org/10.1021/acs.analchem.8b05235, bib file, citations: 185

2017

• Environmental effects on selective dissolution from ZnAlMg alloy under low frequency alternating current perturbations
  V. Shkirskiy, A. Maltseva, K. Ogle, P. Volovitch
  Electrochimica Acta, 238, 397-409, (2017)
  https://doi.org/10.1016/j.electacta.2017.03.210, bib file, citations: 12

• Development of quantitative Local Electrochemical Impedance Mapping: an efficient tool for the evaluation of delamination kinetics
  V. Shkirskiy, P. Volovitch, V. Vivier
  Electrochimica Acta, 235, 442-452, (2017)
  https://doi.org/10.1016/j.electacta.2017.03.076, bib file, citations: 18

2016

• Amino Acid Interleaved Layered Double Hydroxides as Promising Hybrid Materials for AA2024 Corrosion Inhibition
  T. Stimpfling, P. Vialat, H. Hintze‐Bruening, P. Keil, V. Shkirskiy, P. Volovitch, K. Ogle, F. Leroux
  European Journal of Inorganic Chemistry, 2016(13-14), 2006-2016, (2016)
  https://doi.org/10.1002/ejic.201501161, bib file, citations: 45

2015

• On The Time Resolution of the Atomic Emission Spectroelectrochemistry Method
  V. Shkirskiy, P. Maciel, J. Deconinck, K. Ogle
  Journal of The Electrochemical Society, 163(3), C37-C44, (2015)
  https://doi.org/10.1149/2.0991602jes, bib file, citations: 48

• Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings
  V. Shkirskiy, P. Keil, H. Hintze‐Bruening, F. Leroux, P. Vialat, G. Lefèvre, K. Ogle, P. Volovitch
  ACS Applied Materials & Interfaces, 7(45), 25180-25192, (2015)
  https://doi.org/10.1021/acsami.5b06702, bib file, citations: 102

• A Novel Coupling Between Atomic Emission Spectroelectrochemistry and Electrochemical Impedance Spectroscopy: Application to Zn, Zn-Cu and Zn-Al-Mg Alloys
  K. Ogle, V. Shkirskiy, P. Volovitch, P. Zhou, A. Maltseva
  ECS Meeting Abstracts, MA2015-02(11), 629-629, (2015)
  https://doi.org/10.1149/ma2015-02/11/629, bib file

• MoO42− as a soluble inhibitor for Zn in neutral and alkaline solutions
  V. Shkirskiy, P. Keil, H. Hintze‐Bruening, F. Leroux, T. Stimpfling, D. Dragoé, K. Ogle, P. Volovitch
  Corrosion Science, 99, 31-41, (2015)
  https://doi.org/10.1016/j.corsci.2015.05.005, bib file, citations: 37

• A novel coupling of electrochemical impedance spectroscopy with atomic emission spectroelectrochemistry: Application to the open circuit dissolution of zinc
  V. Shkirskiy, K. Ogle
  Electrochimica Acta, 168, 167-172, (2015)
  https://doi.org/10.1016/j.electacta.2015.03.171, bib file, citations: 17

• Methanol dehydration in NaA zeolite membrane reactor
  D. Fedosov, A. Smirnov, V. Shkirskiy, T. Voskoboynikov, І. Іванова
  Journal of Membrane Science, 486, 189-194, (2015)
  https://doi.org/10.1016/j.memsci.2015.03.047, bib file, citations: 39

2014

• Revisiting the Electrochemical Impedance Spectroscopy of Magnesium with Online Inductively Coupled Plasma Atomic Emission Spectroscopy
  V. Shkirskiy, A. King, O. Gharbi, P. Volovitch, J. Scully, K. Ogle, N. Birbilis
  ChemPhysChem, 16(3), 536-539, (2014)
  https://doi.org/10.1002/cphc.201402666, bib file, citations: 105